High-Purity Styrene Monomer (SM) – CAS 100-42-5, Polymer Building Block

Apr 23, 2026 Leave a message

Product brief introduction

High-Purity Styrene Monomer (SM) – The Essential Building Block for Modern Polymers

Shandong RuiShuang Chemical offers premium Styrene Monomer (CAS: 100-42-5) with 99.9% minimum purity and TBC stabilization. This versatile monomer is the foundation for polystyrene (PS), EPS, ABS, SBR rubber, and unsaturated polyester resin production. Available in industrial grade with ISO tank packaging and professional hazardous chemical logistics.

 

Product overview

Styrene Monomer, also known as Vinylbenzene, Ethenylbenzene, or Phenylethylene, with the molecular formula C₈H₈ and CAS number 100-42-5, is a clear, colorless to pale yellow liquid with a characteristic sweet odor . As one of the most important industrial monomers globally, styrene is produced primarily through the catalytic dehydrogenation of ethylbenzene . With a boiling point of 145°C and a flash point of 31°C, it is classified as a flammable liquid . Due to its high reactivity and tendency to polymerize, commercial styrene is typically stabilized with Tert-Butyl Catechol (TBC) to prevent premature polymerization during storage and transport . As the essential building block for polystyrene (PS), expanded polystyrene (EPS), acrylonitrile-butadiene-styrene (ABS), styrene-butadiene rubber (SBR), and unsaturated polyester resin (UPR), styrene is indispensable across packaging, construction, automotive, electronics, and consumer goods industries .

 

Product detail description

What is Styrene Monomer and Why Is It a Critical Industrial Chemical?

In the landscape of industrial chemistry, few monomers match the production volume and versatility of Styrene Monomer. Commonly known as SM, this styrene monomer serves as the starting point for countless plastic and rubber products that define modern life-from foam packaging and insulation to automotive parts and consumer electronics . Its unique vinyl group enables polymerization and copolymerization with various monomers, creating materials with tailored properties for diverse applications .

At Shandong RuiShuang Chemical, we understand that what is styrene extends far beyond its chemical definition. For polymer manufacturers, compounders, and industrial formulators, styrene represents a critical raw material whose quality and stable supply directly impact production efficiency and final product properties. Our role as a trusted styrene supplier is to ensure that this essential monomer reaches you with consistent high purity styrene monomer specifications, proper TBC stabilization, and professional hazardous material handling expertise.

 

 
 
Key Properties of High-Purity Styrene Monomer
Property Typical Value Why It Matters
Purity ≥99.9% Ensures consistent polymerization kinetics; minimizes impurities that could affect molecular weight and polymer properties .
Appearance Clear, colorless to pale yellow liquid Indicates product quality; dark color may suggest degradation or premature polymerization .
Water Content ≤0.03% (300 ppm) Critical for polymerization processes; excess water can act as a chain transfer agent and affect reaction rates .
TBC Content 10-15 ppm (minimum 10 ppm) Stabilized styrene requires TBC to prevent premature polymerization during storage and transport .
Polymer Content ≤10 ppm Low polymer content ensures consistent processing and prevents equipment fouling .
Boiling Point 145°C Determines distillation and recovery conditions; influences reactor design and process safety .
Flash Point 31°C (Closed Cup) Flammable; dictates handling, storage, and transportation protocols .
Density ~0.906 g/mL at 20°C Affects volumetric calculations for reactor charging and shipping .
Vapor Pressure 6 mmHg at 25°C Moderate vapor pressure requires adequate ventilation during use .

 

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The Diverse Applications of Styrene Monomer Across Industries
Industry Sector Primary Application Why Styrene?
Packaging Industry Polystyrene & EPS Styrene for polystyrene production creates PS for rigid packaging and EPS for protective foam packaging .
Construction Insulation & Building Materials Styrene Monomer for EPS is used in foam insulation boards; UPR for fiberglass-reinforced panels and pipes .
Automotive Industry ABS & SBR Styrene for ABS resin produces tough, impact-resistant parts for dashboards and trim; SBR rubber for tires .
Electronics ABS Housings ABS from styrene provides durability and aesthetic finish for appliance and electronics enclosures .
Consumer Goods PS & SAN General-purpose PS for disposable cups and containers; SAN for kitchenware and battery casings .
Coatings & Adhesives Latex & UPR Styrene for latex in paints and coatings; unsaturated polyester resin for gel coats and adhesives .

 

Polystyrene (PS) and Expanded Polystyrene (EPS): The Largest Markets

The largest demand for styrene monomer comes from the production of polystyrene and expanded polystyrene:

Polystyrene (PS) Production:

Process: Free radical polymerization of styrene monomer

Types: General-purpose polystyrene (GPPS) and high-impact polystyrene (HIPS)

Applications: Disposable cups, food containers, CD cases, appliance housings

Expanded Polystyrene (EPS) Production:

Process: Suspension polymerization of styrene with blowing agents

Applications: Protective packaging, insulation boards, lightweight concrete forms

Benefits: Excellent thermal insulation, shock absorption, and lightweight properties

Quality Requirements for PS/EPS:

High purity styrene monomer with low impurities

Consistent TBC levels for controlled polymerization initiation

Low polymer content to prevent defects in final products

 

ABS Resin: Engineering Thermoplastics from Styrene

Styrene for ABS resin is critical for producing one of the most widely used engineering thermoplastics:

ABS Copolymer Production:
ABS is a terpolymer of three monomers:

Acrylonitrile: Provides chemical resistance and heat stability

Butadiene: Provides impact resistance and toughness

Styrene: Provides processability, gloss, and rigidity

Applications of ABS:

Automotive interior and exterior parts

Electronic device housings (computers, TVs, printers)

Appliance components (refrigerator liners, vacuum cleaners)

Plumbing fittings and pipes

LEGO bricks and consumer products

Why Styrene Matters for ABS:

Contributes to the glossy appearance of finished parts

Enables easy processing via injection molding

Provides dimensional stability and rigidity

 

Styrene Butadiene Rubber (SBR): The Tire Industry's Backbone

Styrene for SBR rubber is essential for producing the most widely used synthetic rubber:

SBR Production:

Process: Emulsion or solution copolymerization of styrene and butadiene

Styrene content: Typically 23.5% for general-purpose SBR

Applications: Tires, conveyor belts, hoses, shoe soles, and adhesives

Benefits of SBR:

Excellent abrasion resistance for tire treads

Good aging stability and heat resistance

Superior water resistance compared to natural rubber

Cost-effective alternative to natural rubber

 

Unsaturated Polyester Resin (UPR): Reinforced Composites

Styrene for unsaturated polyester resin serves as both a reactive diluent and crosslinking agent:

UPR Production:

Process: Styrene monomer is mixed with unsaturated polyester prepolymer

Role of styrene: Reduces viscosity for processing and crosslinks the polyester chains

Styrene content: Typically 30-40% in UPR formulations

Applications of UPR:

Fiberglass-reinforced boat hulls and marine components

Automotive body panels (e.g., Corvette)

Bathroom fixtures (sinks, bathtubs, shower stalls)

Corrosion-resistant tanks and pipes

Cultured marble countertops

 

Why Choose Shandong RuiShuang Chemical as Your Styrene Monomer Supplier?

In the specialized world of chemical distribution, expertise and reliability differentiate true partners from mere vendors. Here is why global manufacturers trust us for their styrene bulk supply needs:

1.Strategic Partnerships with Leading Manufacturers:
Our long-standing合作关系 with top-tier Chinese petrochemical companies ensures priority access to high purity styrene monomer from reputable styrene manufacturers. We leverage these relationships to secure competitive pricing and reliable allocation even during market tightness.

2.Comprehensive Quality Assurance:
We understand that industrial grade styrene for polymer production requires rigorous quality control. Every shipment is tested to meet specifications for purity (≥99.9%), water content, TBC content (10-15 ppm), and polymer content. Certificates of Analysis (COA) accompany all deliveries, ensuring full traceability.

3.Specialized Flammable Liquid Logistics with Temperature Control:
Styrene requires specialized handling throughout the supply chain to prevent premature polymerization. Our integrated logistics system is designed specifically for stabilized styrene transport:

Styrene ISO tank containers for efficient bulk transport (20-24 MT) with temperature monitoring

Styrene drums (200kg/55-gallon steel drums) for smaller volume requirements

SM bulk tanker deliveries for large industrial consumers

Experienced carriers certified for flammable materials

Compliance with international shipping regulations (IMDG, IATA, ADR)

4.Flexible Supply Solutions:
We recognize that different customers have different volume requirements:

SM spot cargo for immediate needs

Contract supply for predictable pricing and volume security

Warehouse storage with temperature control for just-in-time delivery

Custom packaging options tailored to your receiving capabilities

5.Technical Expertise and Application Support:
The successful use of styrene requires understanding its polymerization behavior, stabilization requirements, and safety protocols. Our team possesses deep technical knowledge to guide customers on:

Proper storage conditions to maintain styrene shelf life

TBC level verification and management

Regulatory compliance across different jurisdictions

Troubleshooting application challenges

6.Commitment to Safety and Compliance:
Our business philosophy prioritizes safety alongside customer satisfaction. We provide comprehensive safety documentation, including detailed styrene monomer MSDS and handling guidelines, and work with customers to ensure they have the information needed to handle this material safely.

 

📞 Contact our sales team today for a competitive quote and expert consultation.
📧 Email:
Devin@ruishuangchemical.com,Stefan@ruishuangchemical.com
📱 Phone/WhatsApp: +8618653633300,+8613573373908

Partner with us for monomer solutions that drive your success.

 

Frequently Asked Questions - FAQ

Q: What packaging options are available for Styrene Monomer?
A: As a full-service styrene supplier, we offer multiple packaging solutions:

Styrene ISO tank containers (20-24 metric tons) – standard for international bulk transport with temperature monitoring

Styrene drums (200kg/55-gallon steel drums) – for smaller volume requirements

IBC totes (1000kg) – intermediate bulk containers for efficient handling

SM bulk tanker – for large-volume domestic deliveries
All packaging complies with flammable liquid regulations and maintains TBC stabilization .